湘东北地区栗山铅锌铜多金属矿床的成因探讨：来自矿床地质、矿物学和硫同位素的证据

南京大学学报(自然科学版) ›› 2018, Vol. 54 ›› Issue (2): 366–.

湘东北地区栗山铅锌铜多金属矿床的成因探讨：来自矿床地质、矿物学和硫同位素的证据

郭　飞1，2，王智琳1，2*，许德如3，董国军4，宁钧陶4，王　展1，2，邓　腾3，于得水3，崔　宇5

出版日期:2018-03-31 发布日期:2018-03-31
作者简介:1．有色金属成矿预测与地质环境监测教育部重点实验室(中南大学)，长沙，410083；
2．中南大学地球科学与信息物理学院，长沙，410083；
3．中国科学院广州地球化学研究所，中国科学院矿物学与成矿学重点实验室，广州，510640；
4．湖南省地质矿产勘查开发局402队，长沙，410004；
5.湖南省地质测试研究院，长沙，410007
基金资助:
基金项目：国家自然科学基金(41672077，41302049)，科技部国家重点研发计划(2016YFC0600401)，湖南省自然科学基金(2016JJ3143)
收稿日期：2018－01－15
*通讯联系人，E－mail：wangzhilin1025@163.com

Genesis of the Lishan Pb－Zn－Cu polymetallic deposit in northeastern Hunan province：evidences from the geology，mineralogy and sulfur isotopes

Guo Fei1，2，Wang Zhilin1，2*，Xu Deru3，Dong Guojun4，Ning Juntao4，Wang Zhan1，2，Deng Teng3，Yu Deshui3，Cui Yu5

Online:2018-03-31 Published:2018-03-31
About author: 1.Key Laboratory of Metallogenic Prediction of Nonferrous Metals and Geological Environment Monitoring(Central South University)，Ministry of Education；
2．School of Geosciences and Info－Physics，Central South University；
3．CAS Key Laboratory of Mineralogy and Metallogeny，Guangzhou Institute of Geochemistry，Chinese Academy of Sciences；
4．Team 402，Hunan Geology and Mineral Resources Exploration and Development Bureau；
5．Hunan Province Geological Testing Institute

摘要/Abstract

摘要： 湘东北大型栗山铅锌铜多金属矿床位于幕阜山岩体边部，矿体赋存于岩体及其内外接触带中的硅化构造角砾岩带内. 根据野外调查和显微岩(矿)相学观察，可将栗山矿床的主成矿期——热液成矿期划分为四个阶段：粗粒石英＋萤石＋绿泥石(ChlⅠ)＋少量黄铁矿＋黄铜矿阶段(Ⅰ)、石英＋萤石＋绿泥石(ChlⅡ)＋黄铜矿＋黄铁矿阶段(Ⅱ)、石英＋萤石＋绿泥石(ChlⅢ)＋闪锌矿＋黄铜矿＋方铅矿阶段(Ⅲ)、细粒石英＋少量黄铜矿＋黄铁矿细脉阶段(Ⅳ). EPMA分析结果表明ChlⅠ为蠕绿泥石，ChlⅡ和ChlⅢ为鲕绿泥石－铁镁绿泥石. 根据绿泥石温度计，估算出阶段Ⅰ，Ⅱ，Ⅲ的成矿温度分别为239 ℃～280 ℃，221 ℃～261 ℃和212 ℃～238 ℃. 结合闪锌矿硫逸度计算，表明栗山矿床形成于中温、低氧逸度、低硫逸度的环境. 硫化物的δ34S(－4.7‰～1.5‰)变化较小且接近零值，表明成矿流体主要来源于岩浆热液. 通过与钦杭成矿带上典型的铅锌矿床对比，提出栗山矿床为与岩浆热液有关的中温热液充填交代成因．

Abstract: The northeastern Hunan province is located at the central segment of the Jiangnan Orogen known as an economically important Au－Sb－W－Cu polymetallic metallogenic belt. Recently，several Co，Cu，Pb－Zn polymetallic deposits were discovered in northeastern Hunan Province，and they all have a close spatial relationship with the Yanshanian plutons. Among these deposits，the Lishan Pb－Zn－Cu polymetallic deposit occurs within the Mufushan pluton and its contact zone，with orebodies hosted within altered fracture zones. Based on the detailed field investigation and microscopic observation，the Lishan Pb－Zn－Cu polymetallic mineralization can be divided into two epochs：hydrothermal mineralization and supergene enrichment. Furthermore，hydrothermalism can further be subdivided into four stages：coarse quartz＋fluorite＋chlorite(ChlⅠ)＋minor pyrite＋chalcopyrite stage(I)，quartz＋fluorite＋chlorite(ChlⅡ)＋chalcopyrite＋pyrite stage(Ⅱ)，quartz＋fluorite＋chlorite(ChlⅢ)＋sphalerite＋chalcopyrite＋galena stage(Ⅲ)，and fine－grained quartz＋minor pyrite＋chalcopyrite stage(Ⅳ)，from early to late. The EPMA analyses show that ChlⅠ belongs to ripidolite，and that ChlⅡand ChlⅢ are dominated by daphnite and brunsvigite. The empirical geothermometers of chlorite yield temperatures of 239 ℃～280 ℃(av. 255 ℃)，221 ℃～261 ℃(av. 244 ℃)and 212 ℃～238 ℃(av. 231 ℃)for ChlⅠ，ChlⅡ and ChlⅢ，respectively，showing a decreasing trend. The estimated oxygen fugacities lgf(O2)and sulfur fugacities lgf(S2)are －39.90～－34.77 and 0.22～8.41，－42.29～－37.51 and －3.25～4.25，and －43.71～－39.08 and －2.88～1.47 for ChlⅠ，ChlⅡ and ChlⅢ，respectively，suggesting an environment of low oxygen fugacity and low sulfur fugacity. Sphalerite and galena yield δ34S values of －4.7‰ to 1.5‰，suggesting a predominant magmatic sulfur origin. Integrating the geological，mineralogical and sulfur isotopic data documented in this study，as well as the contrast with typical Pb－Zn deposits within the Qin－Hang metallogenic belt，we propose that the Lishan Pb－Zn－Cu polymetallic deposit formed from a hydrothermal system related to the Mufushan pluton，and is of medium－temperature hydrothermal fracture filling type.

郭　飞1，2，王智琳1，2*，许德如3，董国军4，宁钧陶4，王　展1，2，邓　腾3，于得水3，崔　宇5. 湘东北地区栗山铅锌铜多金属矿床的成因探讨：来自矿床地质、矿物学和硫同位素的证据[J]. 南京大学学报(自然科学版), 2018, 54(2): 366–.

Guo Fei1，2，Wang Zhilin1，2*，Xu Deru3，Dong Guojun4，Ning Juntao4，Wang Zhan1，2，Deng Teng3，Yu Deshui3，Cui Yu5. Genesis of the Lishan Pb－Zn－Cu polymetallic deposit in northeastern Hunan province：evidences from the geology，mineralogy and sulfur isotopes[J]. Journal of Nanjing University(Natural Sciences), 2018, 54(2): 366–.

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