新型磷化钴和硫化钴催化剂的制备及其在加氢精制反应中的活性

Preparation of new cobalt phosphide and sulfide catalysts for the hydrotreating reactions
Yamei Yuan, Hui Chen, Danyang Zhao, Chi Wu, Jiao Geng, Jianyi Shen
Fig.5 TEM images of the fresh Co/Al2O3 (a),Co9S8/Al2O3 (b),Co2P/Al2O3 (c) and CoP/Al2O3 (d),as well as the used Co/Al2O3 (a'),Co9S8/Al2O3 (b'),Co2P/Al2O3 (c') and CoP/Al2O3 (d') catalysts for the hydrotreating reactionsReaction conditions: T=533~633 K,P=3.1 MPa,WHSV=2 h-1 and H2∶oil=1500∶1 (vv)