南京大学学报(自然科学版) ›› 2016, Vol. 52 ›› Issue (4): 582.
谭凌艳,杨柳燕,缪爱军*
Tan Lingyan,Yang Liuyan,Miao Aijun*
摘要: 重金属作为传统污染物具有显著生态毒性和健康风险,早在半个世纪之前就引起人们的广泛关注.相比较而言,纳米材料近20年来才被广泛应用于社会生活的各个领域,其潜在的生态风险已有大量报道.但是环境自身是一个非常复杂的介质,不存在单一的重金属或纳米颗粒污染.当重金属与纳米颗粒在环境中共存时,两者之间会发生怎样的相互作用,对各自环境行为与生物效应有何影响,目前并不十分清楚.有限的研究表明,由于纳米颗粒粒径介于1~100 nm之间,比表面积大且其表面存在多种官能团,对重金属离子有较强的吸附作用,从而降低重金属自由离子浓度.此种情况下,重金属在水生生物中的富集、分布与毒性将会发生显著改变.另一方面环境中大量存在的无机离子(如Ca2+,Mg2+等),会降低纳米颗粒的稳定性,使其发生团聚从而改变纳米颗粒的赋存形态与生物效应.
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