南京大学学报(自然科学版) ›› 2015, Vol. 51 ›› Issue (3): 481.
刘晓慧1,2,朱 彬1*,王红磊1,高晋徽1
Liu Xiaohui1,2,Zhu Bin1,*,Wang Honglei1,Gao Jinhui1
摘要: 利用三波段积分浊度仪和Differerntial Optical Absorption Spectroscopy(DOAS)差分吸收光谱仪对南京北郊地区2009~2011年四季气溶胶散射系数和NO2进行观测并结合自动气象场观测数据,计算了南京北郊工业区四季的能见度消光因子贡献率。同时依据2011年5月~2012年4月的PM2.5数据,分析了PM2.5、相对湿度和能见度之间的关系,并得到了不同相对湿度和PM2.5质量浓度下能见度的回归方程。结果表明:气溶胶散射消光贡献(?sa)最大且存在季节差异,冬季最高,夏季最低。PM2.5质量浓度在150~200 μg?m-3时,霾发生概率最高,达到97.7%。相对湿度和PM2.5质量浓度不同,影响能见度的因子不同。
[1] Sisler J F, Malm W C. Interpretation of trends of PM2.5 and reconstructed visibility from the IMPROVE network[J]. Journal of the Air & Waste Management Association, 2000, 50(5): 775~789. [2] Pitchford M, Malm W, Schichtel B, et al. Revised algorithm for estimating light extinction from IMPROVE particle speciation data[J]. Journal of the Air & Waste Management Association, 2007, 57(11): 1326~1336. [3] Malm W C,Sisler D H, ,et al. Spatial and seasonal trends in particle concentration and optical extinction in the United States[J]. Journal of Geophysical Research,1994,99(D1):1347~13701. [4] Chan Y C, Simpson R W, Mctainsh G H, et al. Source apportionment of visibility degradation problems in Brisbane(Astralia)using the multiple linear regression techniques. Atmospheric Environment 1999,33(19):3237~3250. [5] Sisler J F,Malm W C. The relative importance of soluble aerosols to spatial and seasonal trends of impaired visibility in the United States [J]. Atmospheric Environment, 1994,28(5): 851~ 862. [6] 刘新罡,张远航,曾立民等. 广州市大气能见度影响因子的贡献研究[J]. 气候与环境研究, 2006, 11(6): 733~738. [7] 陶 俊, 张仁健, 许振成等. 广州冬季大气消光系数的贡献因子研究[J]. 气候与环境研究, 2009, 14(5): 484~490. [8] 朱李华, 陶 俊, 陈忠明等. 2010 年 1 月北京城区大气消光系数重建及其贡献因子[J]. 环境科学, 2012, 33(1): 13~19. [9] 岳建华, 陶 俊, 林泽健等. 成都春季生物质燃烧和沙尘期间气溶胶散射特征及其重建[J]. 环境科学, 2012, 33(7): 2151~2157. [10] 钱俊龙, 刘红年, 唐丽娟等. 苏州城市灰霾及气溶胶对大气消光贡献的模拟研究[J]. 南京大学学报 (自然科学), 2013, 49(3):311~319 [11] 周淑贞,束 炯.城市气候学.北京:气象出版社,1994,483~496. [12] 麦卡特尼E J.大气光学:分子和粒子散射[M]北京:科学出版社,1988,47. [13] Chan Y C, Simpson R W, Mctainsh G H, et al. Source apportionment of visibility degradation problems in Brisbane(Astralia)using the multiple linear regression techniques. Atmospheric Environment 1999,33(19):3237~3250. [14] Baik N J , Kim Y P, Moon K C. Visibility study in Seoul, 1993. Atmospheric Environment, 1996, 30(13) : 2319 ~2328. [15] Sloane C S.Effect of composition on aerosol light scattering effieffieneies[J].Atmospheric Environment,1986,20(5):1025~1037 [16] Stut Z, Platt U.Numerical analysis and estimation of the statistical error of differential optical absorption spectroscopy measurements with least-squares methods[J] .Appl Opties,1996, 30:6041~6053. [17] Platt U, Perner D, P?tz H W. Simultaneous measurement of atmospheric CH2O, O3,and NO2 by differential optical absorption [J]. Journal of Geophysical Research 84.C10(1979): 6329-6335. [18] Platt U, Perner D, Winer A M, et al. Detection of NO3 in the polluted troposphere by differential optical absorption [J]. Geophysical Research Letters,1980 (7.1): 89~92. [19] Hodkinson R J. Calculations of colour and visibility in urban atmospheres polluted by gaseous NO2.Int J Air Water Pollut,1966,10: 137~144. [20] 中央气象局.地面气象观测规范[M]. 北京:气象出版社, 2003,21-27 [21] 于兴娜, 袁 帅, 马 佳等. 南京北郊2011年春季气溶胶粒子的散射特征[J]. 大气科学学报, 2013, 36(3): 354~360. [22] 高晋徽, 朱 彬, 王东东等. 南京北郊O3, NO2和SO2浓度变化及长/近距离输送的影响[J]. 环境科学学报, 2012, 32(5): 1149~1159. [23] 朱 彤, 尚 静, 赵德峰. 大气复合污染及灰霾形成中非均相化学过程的作用[J]. 中国科学: 化学, 2011 (12): 1731~1740. [24] http://firms.modaps.eosdis.nasa.gov/firemap/[EB/OL]. [25] Pan X L, Yan P, Tang J, et al. Observational study of influence of aerosolhygroscopicgrowth on scattering coefficient over rural area near Beijing mega-city. Atmos Chem Phys, 2009, 9: 7519–7530 [26] Cao J, Wang Q, Chow J C, et al. Impacts of aerosol compositions on visibility impairment in Xi’an, China [J]. Atmospheric Environment, 2012,59: 559~566. [27] Zhao P, Zhang X, Xu X, et al. Long-term visibility trends and characteristics in the region of Beijing, Tianjin, and Hebei, China[J]. Atmospheric Research, 2011, 101(3): 711~718. [28] 游荣高,大气气溶胶浓度和尺度谱分布变化特征及尺度谱分布模式的研究[J].科学探索,1981,1(3):11~22. [29] 孙景群. 能见度与相对湿度的关系[J].气象学报,1985,43(2):230~234. [30] Junge C. The size distribution and aging of natural aerosols as determined from electrical and optical data on the atmosphere[J]. Journal of Meteorology, 1955, 12(1): 13~25. [31] 程雅芳.珠江三角洲新垦地区气溶胶的辐射特性-基于观测的模型研究.北京:北京大学博士论文,2007. [32] 杨 军, 李子华, 黄世鸿. 相对湿度对大气气溶胶粒子短波辐射特性的影响[J]. 大气科学, 1999, 23(2): 239~247. |
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