南京大学学报(自然科学版) ›› 2013, Vol. 49 ›› Issue (3): 331–342.

• • 上一篇    下一篇

 东营凹陷沙河街组砂岩中自生高岭石特征及其成因探讨*

 张雪芬1,陆现彩1**,刘庆2,张林哗2,李娟1,马野牧1,张立虎1
  

  • 出版日期:2015-11-13 发布日期:2015-11-13
  • 作者简介: (1.内生金属成矿机制国家重点实验室,南京大学地球科学与工程学院,南京,210093;
    2.中石化胜利油田分公司地质科学研究院,东营,257015)
  • 基金资助:
     国家自然科学基金(40973029,41072096)

 Characteristics and genetic mechanism of authigenic kaolinite in the
sandstones of the Shahejie formation in the Dongying depression

 Zhang Xue- Fen1 ,Lu Xian-Cai1 ,Zhang Lin-Ye2 ,Liu Qing2 ,Li Juan1
Ma Ye-Mu1,Zhang Li -Hu1   

  • Online:2015-11-13 Published:2015-11-13
  • About author: (1 .State Key Laboratory for Mineral Deposits Rescarch,School of Earth Sciences and Engineering,
    Nanjing University,Nanjing,210093,China;
    2. Geological Science Research institute of Shengli Oilficld,Dongying,257015,China)

摘要:  东营凹陷沙河街组砂岩是胜利油区主要的储集层,自生高岭石是该储层中最常见的自生粘
上.通过显微镜和扫描电镜观察,并结合X射线衍射和电子探针成分分析,发现碎屑粘上含量极少,自生
高岭石为主,其集合体呈书页状和蠕虫状,长石碎屑的溶蚀现象多见;高岭石多充填在次生孔隙内,原生
孔隙中亦可见.通过分析碳酸盐胶结物的碳氧同位素组成研究了砂岩成岩流体与烃源岩间的可能继承
关系,自生高岭石的形成主要受烃源岩成岩演化过程中排出的含烃流体影响,推测酸性的含烃流体与长
石的相互作用是高岭石形成的主要机制.统计表明:高岭石的含量与岩石的孔隙度表现出较好的正相关
性,亦支持其形成于长石溶蚀的观点.

Abstract:  The sandstones of the Shahejie formation in the Dongying depression are the mam reservoms in Shengli
(Oil Field. Kaolinite is the most common authigenic mineral in these reservoirs. By employing multiple techniques in-
cluding scanning electron microscopy(SEM),X-ray diffraction(XRD)and electron probe micro-analyzer(EPMA),it is
confirmed that little elastic clays exist in sandstones while large amount of authigenic kaolinitc have precipitated.The
kaolinite occurs as agglomerates of booklets or vermicular crystals,which generally fill in secondary pores from dis-
solution of feldspars as well as in primary pores. Carbon and oxygen isotopes of carbonate cements were analyzed in
order to better understand the inheritance relationship between diagenesis fluids of sandstones and source rocks.The
results indicate that the fluid released from source rocks accompanying with hydrocarbon generation can result in the
dissolution of elastic feldspar and the formation of authigenic kaolinite. So it is considered that the interaction of acid-
ic hydrocarbon bearing fluid with feldspars is the primary genetic mechanism of anthigenic kaolinites.Statistics anal
ysis shows that the content of kaolinites is well correlated to porosity in reservoirs, and anthigenic kaolinitcs are
closely related to the dissolution of feldspars.

[1]Che Q P,Sun H B, Zhang F L, et al. Authigenic kaolinite orign analysis of paleogene sandstone
reservoirs in Niuju area.Journal of Changchun University of Earth Sciences,l995,25(3):306一
309.(车启鹏,孙洪斌,张凤莲等.牛居地区下第三系砂岩储层中自生高岭石成因分析.长春地质学院学报,1996,25(3):306一309).
[2]El-ghali M A K,Mansurbeg H,Morad S,et al. Dis-tribution of diagenetic alterations in glaciogenic sand-
stones within a depositional facies and sequence stra- tigraphic framework;Evidence from the upper ordo- vician of the Murzuq Basin, SW Libya. Sedimentary  Geology,2006,190:323一351 .
[3]Gier S, Worden R H,Johns W D,et al. Diagencsis and reservoir quality of Miocene sandstones in the
Vienna Basin, Austria. Marine and Petroleum Ge- ology,2008,25:681一695.
[4]Mansurbeg H,Morad S, Salem A, et al. Diagenesis and reservoir quality evolution of palacocene deer
water, marine sandstones, the Shetland-Faroes Ba- sin, British continental shelf. Marine and Petroleum Geology,2008,25:514一543.
[5]Zhang J P,Ge H P,Qin B W. Characteristics of  anthigenic kaolinite in sandstones of Xihu Sag and
it’s impact on reservoir physical properties. Off- shore Oil, 2009,29(1):1一8.(张建培,葛和
平,漆滨汉.西湖凹陷砂岩自生高岭石发育特征及其对储层物性的影响.海洋石油,2009,29 (1):1一8).
[6]Surdam R C,Boese S W , Crossey L J. The chem istry of secondary porosity. AAPG Special Vol umes,1984,37:127一149.
[7]Brantley S L, Stillings L. Feldspar dissolution at  25 ?C and low pH. American Journal of Science,1996,296:101一127.
[8]Wilkinson M, Haszeldine R S, Milliken K L. Cross-Formational flux of aluminium and potassi
um in Gulf Coast(USA)sediments. Special Publi canon of the International Association of Sedim entologists , 2003,34:147一160.
[9]Shaw H F,Conybeare D M. Patterns of clay min- eral diagenesis in interbedded mudrocks and sand-
stones; an example from the Palaeocene of the North Sca. Special Publication of the international
Association of Sedimcntologists, 2003,34:129 ~145.
[10]Worden R H,Morad S. Clay minerals in sand- stones; Controls on formation, distribution and e-
volution. Special Publication of the International Association of Sedimentologists, 2003,34:3 ~31.
[11]Pe-Piper G, Dolansky L, Piper D J W. Sedimentary environment and diagenesis of the Lower Cretaceous
Chaswood Formation, southeastern Canada; The ori- gin of kaolirrrich mudstones. Sedimentary Geology, 2005,178:7一97.
[12]Liu X D,Lu X C,Wang R C,et al. In silico calcu-lation of acidity constants of carbonic acid con-
formers. Journal of Physical Chemistry A,2010 ,114(49).129141一12917.
[13]Bj?rlykke K,Brendsdal A. Diagenesis of the Brent Sandstone in the Statfjord field,North Sea. The
Society of Economic Paleontologists and Mineral- ogists,1986,38:157一167.
[14]Bath A H,Milodowskiand A E,Strong G E. Fluid flow and diagenesis in the East Midlands Triassic
sandstone aquifer. Geological Society, London, Special Publications, 1987,34:127一140.
[15]Jiao Zunsheng, Surdam R C. Stratigraphic/diage- netic pressure seals in the muddy sandstone,
Powder River Basin, Wyoming. AAPG Special Volumes,1994,61:297一312.
[16]Franca A B, Araujo L M, Maynard J B, et al. Sec- ondary porosity formed by deep meteoric leaching;
Botucatu eolianite, southern South America. AAPG Bulletin,2003,87(7):1073一1082.
[17]Huang S J,Wu W H,Liu J,et al. Generation of secondary porosity by meteoric water during time
of subacrial exposure. Earth Sciene-Journal of China University of Geosciences,2003,28(4):
419-428.(黄思静,武文慧,刘洁等.大气水在碎屑岩次生孔隙形成中的作用—以鄂尔多斯
盆地三叠系延长组为例.地球科学一中国地质大学学报,2003,28(4) :419-428).
[18]Cookenboo H O,Bustin R M. Pore water evolution in sandstones of the Groundhog Coalfield,northern
Bowser Basin, British Columbia. Sedimentary Geolo- gY,1999,123:129一146.
[19]Lanson B,Beaufort D,Berger G,et al. Authigenic kaolin and illitic minerals during burial diagenesis
of sandstones;A review. Clay Minerals,2002,37: 1~22.
[20]Brosse E,Margueron T,Cassou C,et al. The forma- tion and stability of kaolinite in Brent sandstone res
ervoirs; a modelling approach. Special Publication of the international Association of Sedimcntologists, 2003,34:383一108.
[21]Marfil R,Delgado A,Rossi C,et al. Origin and diagenetic evolution of kaolin in reservoir sand-
stones and associated shales of the Jurassic and Cretaceous,Salam Field,Western Desert(E-
gypt).Special Publication of the international As- sociation of Sedimentologists, 2003,34: 319一342.
[22]Milliken K. Microscale distribution of kaolinite in Breathitt Formation sandstones(middle
Pennsylvanian):Implications for mass bal- ance. Special Publication of the international
Association of Scdimcntologists,2003,34: 343一360.
[23]Zou H Y,Hao F,Liu G D,et al. Genesis of anthi- genie kaolinite and gas accumulation in Bashijiqi-
ka Fm sandstone in Kuqa thrust belt. Oil and Gas Geology,2005,26(6):786一792.(邹华耀,郝 芳,柳广弟等.库车冲断带巴什基奇克组砂岩自生高岭石成因与油气成藏.石油与天然气地质, 2005,26(6):786一992).
[24]Islam M A. Diagenesis and reservoir quality of Bhuban sandstoncs(Neogene),Titas Gas Field,
Bengal Basin, Bangladesh. Journal of Asian Earth Sciences, 2009,35:89一100.
[25]Ruiz Cruz M D, Reyes E. Kaolinite and dickite formation during shale diagenesis; isotopic data.
Applied Geochemistry, 1998,13:95一104.
[26]Uysal I T,Golding S D, Baublys K. Stable isotope geochemistry of authigenic clay minerals from
Late Permian coal measures,Queensland,Aus-tralia;Implications for the evolution of the Bowen
Basin. Earth and Planetary Science Letters,2000,180:149~162.
[27]Morad S,Worden R H,Ketzer J M. Oxygen and hy- drogen isotopic composition of diagenetic clay miner-
als in sandstones; A review of the data and controls. Special Publication of the International Association
of Sedimentologists,2003,34:63一91.
[28]Antonio Emídio do Araújo dos Santos Jr,Dilce de Fatima Rossctti,Haydn H. Murray. Origins of
the Rio Capim kaolinites(northern Brazil)re- vealed by δ18 O and δD analyses. Applied Clay Sci- ence,2007,37.281一294.
[29]Ochoa M, Arribas J,Mas R,et al. 2007. Destrur tion of a fluvial reservior by hydrothermal acivity
(Cameros Basin, Spain).Sedimentary Geology, 2007,202:158一173.
[30]Berrocoso á J,Zuluaga M C,Elorza J. Diagenesis,palaeoclimate and tectono-sedimentary influences
on clay mineralogy and stable isotopes from Up- per Cretaceous marine successions of the Basques
Cantabrian Basin(N Spain).Cretaceous Re- search,2008,29:386一404.
[31]Bechtel A, Savin S M, Hoernes S. Oxygen and hy- drogen isotopic composition of clay minerals of the
Bahloul Formation in the region of the Bou Grine zinc-lead ore deposit(Tunisia):Evidence for fluid-
rock interaction in the vicinity of salt dome cap rock. Chemical Geology, 1999,156:191一207.
[32]Uysal I T,Golding S D,Glikson M. Pectrographic and isotope constraints on the origin of authigenic
carbonate minerals and the associated fluid evolu- tion in Late Permian coal measures, Bowen Basin
(Queensland),Australia. Sedimentary Geology, 2000,136.189一206.
[33]Chen X, Zhong J H,Yuan J,et al. Development and formation of paleogene kaolinite,Bonan sub-
sag. Petroleum Exploration and Development,2009,36(4):456一463.(陈鑫,钟建华,袁静
等.渤南洼陷占近系高岭石发育特征及转化机理.石油勘探与开发,2009,36(4) :456-463).
[34]Wolela A M, Gierlowski-Kordesch E H. Diage- netic history of fluvial and lacustrinc sandstones
of the Hartford Basin(Triassic-Jurassic),Newark Supergroup,USA. Sedimentary Geology, 2007,197:99一126.
[35]Wolela A. Diagenetic evolution of the Ansian-Pliensbachian Adigrat Sandstone,Blue Nile Ba-
sin, Ethiopia. Journal of African Earth Sciences,201——56:29~42.
[36]Zhu X M, Zhong D K , Zhang Q, et al. The charar teristics and evaluation of palcogene elastic reser-
voir, Jiyang Depression. Beijing; Science press,2008, 17-35.(朱筱敏,钟大康,张琴等.济阳
坳陷占近系碎屑岩储层特征和评价.北京:科学出版社,2008,17一35).
[37]Gu J Y,He B. Study on Triassic fan delta sedim- ention and reservoir in Lunnan area,Tarim basin.
A cta Scdimentologica Sinica, 199,12(2):54一62.(顾家裕,何斌.塔里术盆地轮南地区三叠
系扇三角洲沉积与储集层研究.沉积学报,1994,12 (2):54一62).
[38]Fu W J, Influence of clay minerals on sandstone reservoir properties. Journal of Palaeogeography,
2000,2(3):59-68.(伏万军.粘上矿物成因及对砂岩储集性能的影响.占地理学报,2000,2(3): 59一68).
[39]Hu J N,Zhang S N,Li D M.The influence of dia- genesis on reservoir quality in Shihezi-Shanxi
Formation in Northern Ordos Basin. Journal of Chengdu University of Technology, 2001,28(2): 169-173.(胡江奈,张哨楠,李德敏.鄂尔多斯盆地北部下石盒子组一山西组成岩作用与储层的关系.成都理工学院学报,2001,28(2):169-173).
[40]Zhu S Q, Huang S J,Yao P,et al. The kaolinite cementation and reservoir assessment of the Up-
per Triassic Chang一2 pay set in the Jiyuan re gion, shaanxi. Sedimentary Geology and Tethyan
Geology,2006,26(1);88 -91.(朱世全,黄思静,姚鹏等.姬源地区上三叠统长2油层组高岭石
胶结与储层评价.沉积与特提斯地质,2006,26 (1):88一91).
[41]Wang Y H,Qian K. Geological research and ex- ploration practice of Shengli oil field. Shangdong;
University of Petroleum Press,1992,34.(王秉海,钱凯.胜利油区地质研究与勘探实践.山东: 石油大学出版社,1992,30.
[42]Zhang L Y,Liu Q, Zhang C R. Study on the ge netic relationship between hydrocarbon occur-
rence and poolslormation in Dongying Depres- sion. Beijing; Geology Publishing House,2005,
159-188.(张林哗,刘庆,张春荣.东营凹陷成烃与成藏关系研究.北京:地质出版社,2005,159 一188).
[43]Jiang H C,Luo J Q. Study on main oil-gas migration pathway and reservoir forming rule in Jiyang depres-
sion. Petroleum Ucology and Recovery Efficiency, 2005,12(1):18-20.(姜慧超,罗佳强.济阳坳陷油
气主运移通道及成藏规律研究.油气地质与采收率,2005,12(1):18一20).
[44]Su Y J,Jiang Y L,Fang X N. New compre hension on the forming mechanism of primary
lithologic oil reservoir. Petroleum Geology and Recovery Efficiency,2006,13(2):37一40.
(苏永进,蒋有录,房新娜.原生岩性油藏形成机理新解.油气地质与采收率,2006,13 (2): 37一40).
[45]Li S M, Qiu G Q, Jiang Z X , et al. Origin of the subtle oils in the Niuzhuang Sag. Earth Science
Journal of China University of Geosciences,2007,32(2);213-218.(李素梅,邱桂强,姜振学等.牛
庄洼陷“岩性油气藏”油气成因.地球科学一中国地质大学学报,2007,32(2);213-218).
[46]Zhuo Q G. Effects of abnormal higlrpressure on the hydrocarbon-forming mechanism of source
rocks and thcmigration and accumulation of oil and gas. Petroleum Geology and Experiment,
2007,27(2):169-174.(卓勤功.异常高压对烃源岩成烃机理和油气运聚成藏的影响.石油实验地质,2009,27(2):169一174.
[47]Koukouvclas I K,Papoulis D. Fluid involvement in the active Hclike normal Fault, Gulf of Cor-
inth,Greece.Journal of Structural Geology,2009,31:237一250.
[48]Liu Q, Zhang L Y,Shen Z M,et al. Microfracture occurrence and its significance to the hydrocarbon
expulsion in source rocks with high organic mat- ter abundance,Dongying Depression. Geological
Review. 2004 , 50 ( 6 ) : 593 - 598.(刘庆,张林哗,沈忠明等.东营凹陷富有机质烃源岩顺层微
裂隙的发育与油气运移.地质论评,2004,50(6): 593一598).
[49]Momper J A.Oil migration limitations suggested by geological and geochemical consideration.
AAPG Course Note Series, 1978,8,B1一B60.
[50]Lev V, Charles L. Elastic anisotropy of source rock:implications for hydrocarbon generation and
primary migration. AAPG Bulletin, 1996,50: 531~544
[51]Heydari E, Wade W J. Massive recrystallization of low-Mg calcite at high temperatures in hydro-
carbon sonrce rocks; Implications for organic acids as factors in diagenesis. AAPG Bulletin,2002, 86(7).1285一1303.
[52]Zhang J , Peng X Q, Jiang Z X , et al. Primary hy drocarbon migration paths and evidence in Lower
Es3, source rock, Niuzhuang-Liuhu Sag, Dongying Depression, China. Acta Geologica Sinica, 2007,
81(2) ;261 -267.(张俊,庞雄奇,姜振学等.东营凹陷牛庄一六户洼陷沙河街组三段下亚段烃源
岩排烃通道及证据.地质学报,2007, 81 (2); 261一267).
[53]Zhao X Y,Zhang Y Y. Clay minerals and clay mineral analysis. Beijing:Maritime Press. 1990.
(赵杏媛,张有瑜.粘上矿物与粘上矿物分析.北京:海洋出版社,1990).
[54]Song M S. Diagenwsis of the member 4 of the Shahejic Formation in the south slope of the
Dongying depression, China. Journal of Chengdu University of Technology(Sciwnce g- Technology
Edition) , 2005 , 32 ( 3 ) : 239 - 245.(宋明水.东营凹陷南斜坡东部地区沙四段储层成岩作用研究.
成都理工大学学报(自然科学),2005, 32 ( 3 ) 239一245).
[55]Zhang G L,Chen S Y,Yan J H,et al. Mineral characteristics of kaolinite in Z hengjia-wang-
zhuang areas and their effect on reservoir quality. Assembly of sequence stratigraphy in the fourth
oil and gas.2005,329-336.(张关龙,陈世悦,焉仔继华等.郑家、土庄地区沙三段高岭石矿物特征
及对储层物性的影响.全国第四届油气层序地层学大会,2005,329-336).
[56]Wang J F. Sedimentary facics of the Shahejie Forma- tion of Paleogene in Dongying Sag, Jiyang Depres- sion. Journal of Palaeogeography, 2005,7(1):45一58.(王居峰.济阳坳陷东营凹陷占近系沙河街组沉积相.占地理学报,2005,7(1):45-58).
[57]Zhang Z, Chen X M, Zhao M. The use of the mixed-layer illite/smectite to trace the palcotem-
perature and the eroded strata thickness in the Jiyang basin, eastern China. Journal of Nanjing
University(Natural Sciences) ,2008,44(6):621一631.(张析,陈小明,赵明.利用伊蒙混层矿
物对山东济阳坳陷占地温和剥蚀深度的反演.南京大学学报(自然科学),2008, 44( 6 ) : 621 - 631).
[58]Girard J P,Munz I A,Johansen H,etal. Diagene- sis of the Hild Brent sandstones, Northern North
Sea;isotopic evidence for the prevailing influence of deep basinal water. Journal of Sedimentary Re- search,2002,72(6):746一759.
[59]Calvo R,Ayalon A,Bcin A, et al. Chemical and i- sotopic composition of diagenetic carbonate ce- menu and its relation to hydrocarbon accumula- tion in the Heletz-Kokhav oil field(lsrael).Jour- nal of Geochemical Exploration, 2011,108:88 ~98.
[60]Zhang X F,Lu X C,Zhang L Y,et al. Diagenesis of source rocks and sandstones of Shahejic Foi-
mation and their petroleum geological significance in Niuzhuang Sulrsag, Shengli oil field. Geolog-
ical Review,2013,59(2):287一299.(张雪芬,陆现彩,张林哗等.胜利油区牛庄洼陷沙河街组烃
源岩和砂岩的协同成岩作用及其石油地质意义. 地质论评,2013,59(2):287-299).
[61]Land L S.The isotopic and trace element geo- chemistry of dolomite:The state of the art. AAPG Bulletin.1979,63. 485.
[62]Solano-Acosta W, Schimmclmann A, Mastalerz M, et al. Diagenetic mineralization in Pennsylvanian coals
from Indiana, USA;13 C/12 C and18O/16O implications for cleat origin and coalbed methane generation.
international Journal of Coal Geology, 2008,73: 219一236.
[63]Shi D S, Xic B Y,Mcng F W.The occurrence of NaCl-CaCl2一H2O system fluid inclusions in
sandstones of Dongying depression, Shandong, and the significance. Journal of Nanjing Universi-
ty(Natural Sciences),2012,48(3):308一315.(石砒石,解宝玉,孟凡巍.山东东营凹陷砂岩中
NaCl-CaCl2-H2O体系包裹体的发现及其意义.南京大学学报(自然科学),2012,48(3):308 一315).
[64]Cao J,Zhang Y J,Hu W X, et al. Developing characteristics of kaolinite in central Junggar ba-
sin and their effect on the reservoir quality. Acta Mineralogica Sinica, 200,25 (4):367一373.(曹
剑,张义杰,胡文暄等.油气储层自生高岭石发育特点及其对物性的影响.矿物学报,2005,25 (4):367一373).
[65]Luo J L,Liu X H,LinT,et al. Impact od diagen- esis and hydrocarbon emplacement on sandstone
reservoir quality of the Yanchang Formation(Up- per Triassic) in the Ordos Basin. Acta Geologica
Sinica,2006,80(5):664-673.(罗静兰,刘小洪,林憧等.成岩作用与油气侵位对鄂尔多斯盆地
延长组砂岩储层物性的影响.地质学报,2006,80 (5):664一693).
[66]Yin G, Ni S J,Shi Z M,et al. isotope Geochemis- try. Beijing;Geology Publishing House,2009,264
一296.(尹观,倪师军,施泽明等.同位素地球化学.北京:地质出版社,2009,264-296).
[67]Irwin H,Curbs C, Coleman M, isotopic evidence for source of diagenetic carbonates formed during
burial of organirrich sediments. Natural,1977,269:209一213.
[68]Fröhlich S,Redfern J,Petitpierre L,et al. Diage- netic evolution of incised channel sandstones; im-
plications for reservoir characterisation of the Lower Carboniferous Marar Formation, Gha-
dames Basin, Western Libya. Journal of Petrole- um Geology, 2010,33(1):3一18.
[69]Shi D S, Xic B Y, Meng F W.The occurrence of NanCl一CaCl2一H2Osystem fluid inclusions in
sandstones of the Dongying depression, Shandong, and the significance. Journal of Nanjing University;
Nat Sci Ed,2012,48(3);308-315.(石砒石,解宝玉,孟凡巍.山东东营凹陷砂岩中NaCl- CaCl2
H2O体系包裹体的发现及其意义.南京大学学报(自然科学),2012,48(3);308-315).
[70]Zhang S W.“Water consumption" in diagenetic stage and its petroleum geological significance.
Acta Sedimentologica Sinaca, 2006,4(4):1一6. (张善文.成岩过程中的“耗水作用”及其石油地质意义.油气地球物理,2006,4(4):1-6).





No related articles found!
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
No Suggested Reading articles found!