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[1]赵玉敏,万海勤*,许昭怡.碳纳米管吸附还原溴酸盐研究[J].南京大学学报(自然科学版),2017,53(二):286.[doi:10.13232/j.cnki.jnju.2017.02.009]
 Zhao Yumin,Wan Haiqin*,Xu Zhaoyi.Adsorption and reduction of bromate over carbon nanotubes[J].Journal of Nanjing University(Natural Sciences),2017,53(二):286.[doi:10.13232/j.cnki.jnju.2017.02.009]
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碳纳米管吸附还原溴酸盐研究()
     

《南京大学学报(自然科学版)》[ISSN:0469-5097/CN:32-1169/N]

卷:
53
期数:
2017年第二期
页码:
286
栏目:
出版日期:
2017-04-01

文章信息/Info

Title:
Adsorption and reduction of bromate over carbon nanotubes
作者:
赵玉敏万海勤*许昭怡
污染控制与资源化研究国家重点实验室,南京大学环境学院,南京,210023
Author(s):
Zhao YuminWan Haiqin*Xu Zhaoyi
State Key Laboratory of Pollution Control and Resource Reuse,School of the Environment, Nanjing University,Nanjing,210023,China
关键词:
碳纳米管溴酸盐吸 附还 原
Keywords:
carbon nanotubesbromateadsorptionreduction
分类号:
X131.2
DOI:
10.13232/j.cnki.jnju.2017.02.009
文献标志码:
A
摘要:
以单壁碳纳米管(single walled carbon nanotubes,SWCNTs)和多壁碳纳米管(multiwalled carbon nanotubes,MWCNTs)作为原料,经过硝酸处理后分别在800 ℃、950 ℃和1100 ℃下焙烧得到S?800、S?950、S?1100、M?800、M?950和M?1100系列吸附材料.测试其对饮用水中溴酸盐的吸附性能,结果发现反应48 h后单壁碳纳米管对0.5 mg·L-1、1.0 mg·L-1和5.0 mg·L-1溴酸盐去除率高于多壁碳纳米管;随着焙烧温度升高,碳纳米管对溴酸盐的去除率显著增强.此外还发现,经过4次循环使用后碳纳米管去除溴酸盐的效率无明显降低.为了探讨碳纳米管对溴酸盐的吸附去除机制,对制备的材料进行了氮气吸脱附Brunauer?Emmett?Teller(BET)、Transmission electron microscopy(TEM)、X?ray diffraction(XRD)、Raman spectroscopy(Raman)、X?ray photoelectron spectroscopy(XPS)、Zeta电位等性质表征.结果发现反应过后碳纳米管表面氧元素含量显著增加,通过不同温度焙烧得到的材料其等电点也有显著差异.
Abstract:
A series of single walled carbon nanotubes(SWCNTs)and multiwalled carbon nanotubes(MWCNTs)were prepared via pretreating with nitric acid and calcining at different temperatures,and their performances of bromate removal were tested.The results indicated that SWCNTs displayed higher removal rate than that of MWCNTs,and the bromate removal rate of the adsorbents was dependent on the calcining temperature.Bromate removal rate increased with calcining temperatures.The prepared CNTs were characterized by BET,TEM,XRD,Raman,XPS and Zeta potentials.The XPS results showed that the amount of surface O atoms of the adsorbents was increased after adsorbing bromate.The Zeta potential results indicated that the IEPs of the adsorbents were changed with calcining temperatures.

参考文献/References:

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备注/Memo

备注/Memo:
基金项目:江苏省自然科学基金(BK2010378) 收稿日期:2016-11-12 *通讯联系人,E-mail:wanhq@nju.edu.cn
更新日期/Last Update: 2017-03-26